What did Svante Arrhenius note about reactive acids?
Reactive acids generally contain oxygen or are hydrogen halides.
How did Arrhenius define an acid?
An acid is a compound with a dissociable hydrogen ion (H+).
What happens during a neutralization reaction?
The hydrogen ion combines with a hydroxide ion (OH-) to produce water.
What are bases according to Arrhenius?
Bases are compounds that contain OH in their formula.
What limitation did Arrhenius's theory have regarding ammonia?
It could not explain why ammonia (NH3) had base properties.
How does the Brønsted-Lowry theory define acids?
Brønsted-Lowry acids donate a proton (H+) during a reaction.
How does the Brønsted-Lowry theory define bases?
Brønsted-Lowry bases accept a proton during a reaction.
What is an amphiprotic compound?
A compound that can act as both an acid and a base.
What is a conjugate acid?
A conjugate acid is formed when a base gains a proton (H+).
What defines a strong acid?
Strong acids ionize completely with no equilibrium.
What defines a weak acid?
Weak acids ionize partially, establishing an equilibrium.
What are the six main strong acids?
Which HX acid is the only weak acid?
HF is the only weak acid in Group VIIA.
How does the number of oxygens affect oxoacids?
As the number of oxygens increases, the acidity increases.
What weakens the O-H bond in oxoacids?
Oxygen atoms pull electron density away from the O-H bond.
What is the equation for weak acid ionization?
HA + H2O ⇌ H3O+ + A-
What is the acid ionization constant?
Ka
What is the equation for strong base dissociation?
NaOH → Na+ + OH⁻
What is the equilibrium equation for weak bases?
NH3 + H2O ⇌ NH4+ + OH⁻
What is the water ionization equation?
H2O (l) + H2O (l) ⇌ H3O⁺(aq) + OH⁻ (aq)
What is the water ionization constant at 25°C?
Kw = 1.0 x 10-14
What indicates an acidic solution?
[H3O+] > [OH-]
What is the pH formula?
pH = -log[H3O⁺]
What pH indicates a basic solution?
pH > 7
What is the relationship between pH and pOH?
14 = pH + pOH
How do we find [OH-] from [H3O+]?
Use Kw = [H3O+][OH⁻]=1.0 x 10-14
What is the equilibrium constant for weak bases?
Kb
How do we find the pH of weak acids?
Use an ICE box to find [H3O+] at equilibrium.
What is the pH of 0.867 M benzoic acid?
Calculate using Ka=6.3 x 10-5 and ICE table.
How do we find Ka from measured pH?
Use ICE box and known initial concentration.
What is the pH of 0.30M HCN?
pH = 5.87
What is the pH of 0.055 M butanoic acid solution?
2.72
What is the dissociation reaction of butanoic acid?
ButH + H2O ⇌ But⁻ + H3O⁺
What type of acid is butanoic acid?
Weak monoprotic acid
What is the formula to calculate Ka?
Ka = ?rac{[H3O^+][But^-]}{[ButH]}
How to find [H3O⁺] from pH?
[H3O⁺] = 10^{-pH}
What is the [H3O⁺] concentration at pH 2.72?
[H3O⁺] = 0.0019 M
What is the Ka of butanoic acid based on the given data?
Ka = 0.000238
What did Svante Arrhenius note about reactive acids?
Reactive acids generally contain oxygen or are hydrogen halides.
What happens during a neutralization reaction?
The hydrogen ion combines with a hydroxide ion (OH-) to produce water.
What limitation did Arrhenius's theory have regarding ammonia?
It could not explain why ammonia (NH3) had base properties.
How does the Brønsted-Lowry theory define acids?
Brønsted-Lowry acids donate a proton (H+) during a reaction.
How does the Brønsted-Lowry theory define bases?
Brønsted-Lowry bases accept a proton during a reaction.
How does the number of oxygens affect oxoacids?
As the number of oxygens increases, the acidity increases.
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